Semiconductor devices and methods of fabricating the same

ABSTRACT

Semiconductor devices are provided. A semiconductor device includes gaps between conductive patterns. Moreover, the semiconductor device includes a permeable layer on the conductive patterns. Methods of fabricating semiconductor devices are also provided.

CROSS-REFERENCE TO RELATED APPLICATION

This U.S. non-provisional patent application claims priority under 35U.S.C. §119 to Korean Patent Application No. 10-2013-0167196, filed onDec. 30, 2013 in the Korean Intellectual Property Office (KIPO), thecontents of which are hereby incorporated by reference herein in theirentireties.

BACKGROUND

The present disclosure relates to semiconductor devices. Semiconductordevices may trend toward higher integration, higher density, lower powerconsumption, and faster operating speeds. A semiconductor device withhighly integrated circuits may include a multi-layered interconnectionstructure, which may be formed of a metal material (e.g., aluminum). Forexample, the formation of aluminum interconnection lines may includedepositing an aluminum layer on an insulating layer and etching it toexpose the insulating layer.

The use of copper, instead of aluminum, as a material forinterconnection lines, may increase as a design rule of semiconductordevices decreases. This may be due to the relatively high electricalresistivity of aluminum. For example, as a width of an aluminum linedecreases, its resistance increases, and thus it may be a difficult torealize semiconductor devices with higher operating speeds. Copper mayoffer advantages in cost and electrical conductivity, but there may bedifficulty in patterning a copper layer using an etching technique. Adamascene process may also be used to form copper interconnection lines.

Further, due to the increasing integration density of semiconductordevices, a space between interconnection lines may become narrower andnarrower, and this may cause electrical interference betweeninterconnection lines and a delay in a signal transfer speed, despitethe use of copper interconnection lines.

SUMMARY

An aspect of the present inventive concepts provides a semiconductordevice having an air gap. Another aspect of the present inventiveconcepts provides a method of fabricating a semiconductor device havingan air gap.

In one example embodiment, a semiconductor device may include asubstrate including a first region and second regions, a plurality offirst conductive patterns on the first region and a plurality of secondconductive patterns on the second region, respectively, an insulatingdiffusion barrier layer covering sidewalls and upper surfaces of thefirst and second conductive patterns, a permeable layer on theinsulating diffusion barrier layer, a first air gap between theplurality of first conductive patterns, a second air gap between theplurality of second conductive patterns, and wherein the first air gapis defined by sidewalls and an upper surface of the insulating diffusionbarrier layer, and wherein the second air gap is defined by sidewallsand an upper surface of the insulating diffusion barrier layer and abottom surface of the permeable layer.

In some embodiments, the permeable layer may be spaced apart from thefirst air gap.

In some embodiments, the insulating diffusion barrier layer may bethinner on a bottom of the first air gap than on a bottom of the secondair gap.

In some embodiments, the insulating diffusion barrier layer may bethinner on the sidewall of the first conductive patterns than on thesidewall of the second conductive patterns.

In some embodiments, the permeable layer may be disposed on both of thefirst and second regions.

In some embodiments, the semiconductor device may further include athird conductive pattern on a boundary of the first and second regions,wherein the insulating diffusion barrier layer covers both sidewalls ofthe third conductive pattern. The insulating diffusion barrier layer maybe thinner on a sidewall of the third conductive pattern adjacent to thefirst region than on other sidewall of the third conductive patternadjacent to the second region.

In some embodiments, the semiconductor device may further include aprotection layer between the insulating diffusion barrier layer and theupper surfaces of the first and second conductive patterns.

In some embodiments, the semiconductor device may further include ametal diffusion barrier layer covering the sidewalls and the bottom ofthe first and second conductive patterns.

In accordance with another aspect of the present inventive concepts, asemiconductor device may include a plurality of first conductivepatterns on a substrate, a first insulating diffusion barrier layercovering sidewalls and upper surfaces of the first conductive patterns,a first permeable layer on the first insulating diffusion barrier layer,a plurality of second conductive patterns on the first permeable layer,a second insulating diffusion barrier layer covering sidewalls and uppersurfaces of the second conductive patterns, a second permeable layer onthe second insulating diffusion barrier layer, a first air gap betweenthe plurality of first conductive patterns, a second air gap between theplurality of second conductive patterns. The first air gap is defined bysidewalls and an upper surface of the first insulating diffusion barrierlayer. The second air gap is defined by sidewalls and an upper surfaceof the second insulating diffusion barrier layer and a bottom surface ofthe second permeable layer.

In some embodiments, the first permeable layer may be spaced apart fromthe first air gap.

In some embodiments, the first insulating diffusion barrier layerdisposed on a bottom of the first air gap may be thinner than the secondinsulating diffusion barrier layer disposed on a bottom of the secondair gap.

In some embodiments, the semiconductor device may further include afirst protection layer between the first insulating diffusion barrierlayer and the upper surfaces of the first conductive patterns.

In some embodiments, the semiconductor device may further include asecond protection layer between the second insulating diffusion barrierlayer and the upper surfaces of the second conductive patterns.

In some embodiments, the semiconductor device may further include afirst metal diffusion barrier layer covering the sidewalls and thebottom of the first conductive patterns.

In some embodiments, the semiconductor device may further include asecond metal diffusion barrier layer covering the sidewalls and thebottom of the second conductive patterns.

In accordance with still another aspect of the present inventiveconcepts, a semiconductor device may include a plurality of firstconductive patterns on a substrate, a first insulating diffusion barrierlayer covering sidewalls and upper surfaces of the first conductivepatterns, a first permeable layer on the first insulating diffusionbarrier layer, a plurality of second conductive patterns on the firstpermeable layer, a second insulating diffusion barrier layer coveringsidewalls and upper surfaces of the second conductive patterns, a secondpermeable layer on the second insulating diffusion barrier layer, afirst air gap between the plurality of first conductive patterns, asecond air gap between the plurality of second conductive patterns. Thefirst air gap is defined by sidewalls and an upper surface of the firstinsulating diffusion barrier layer and a bottom surface of the firstpermeable layer. The second air gap is defined by sidewalls and an uppersurface of the second insulating diffusion barrier layer.

In some embodiments, the second permeable layer may be spaced apart fromthe second air gap.

In some embodiments, the first insulating diffusion barrier layerdisposed on a bottom of the first air gap may be thicker than the secondinsulating diffusion barrier layer disposed on a bottom of the secondair gap.

In some embodiments, the semiconductor device may further include afirst protection layer between the first insulating diffusion barrierlayer and the upper surfaces of the first conductive patterns.

In some embodiments, the semiconductor device may further include asecond protection layer between the second insulating diffusion barrierlayer and the upper surfaces of the second conductive patterns.

In accordance with still another aspect of the present inventiveconcepts, a method of manufacturing a semiconductor device may includeforming first and second conductive patterns on first and secondregions, respectively, of a substrate. The first conductive patterns maybe formed to be spaced apart from each other with a first space, and thesecond conductive patterns may be formed to be spaced apart from eachother with a second space that is larger than the first space. Themethod may further include forming an insulating diffusion barrier layerto cover side and top surfaces of the first and second conductivepatterns and define a first air gap between the first conductivepatterns, forming a sacrificial layer pattern to fill a space betweenthe second conductive patterns, forming a permeable layer on theinsulating diffusion barrier layer and the sacrificial layer pattern,and removing the sacrificial layer pattern to form a second air gap.

In some embodiments, the forming of the first and second conductivepatterns may include forming an interlayer insulating layer on thesubstrate to include first recess regions spaced apart from each otherwith the first space on the first region and second recess regionsspaced apart from each other with the second space on the second region,forming the first and second conductive patterns in the first and secondrecess regions, respectively, and etching the interlayer insulatinglayer to expose the side surfaces of the first and second conductivepatterns.

In some embodiments, the method may further include forming a protectionlayer to cover top surfaces of the first and second conductive patterns,before the etching of the interlayer insulating layer.

In some embodiments, the protection layer may be formed of at least oneof metals including tantalum, ruthenium, cobalt, manganese, titanium,tungsten, nickel, and aluminum, oxides of the metals, nitrides of themetals, or oxynitrides of the metals.

In some embodiments, the sacrificial layer pattern may be formed of ahydrocarbon layer, and the removing of the sacrificial layer pattern mayinclude an ashing process, which may be performed to transform thesacrificial layer pattern into a gas phase and exhaust the gas throughthe permeable layer.

In some embodiments, the insulating diffusion barrier layer may beformed of at least one of silicon carbon nitride (SiCN), silicon nitride(SiN), or silicon oxycarbide (SiOC).

In some embodiments, the insulating diffusion barrier layer may beformed to may have a thickness of 70 Å or thicker, on the side surfaceof the second conductive pattern.

In some embodiments, the method may further include forming a thirdrecess region in the permeable layer, before the removing of thesacrificial layer pattern, and then, forming a third conductive patternin the third recess region.

BRIEF DESCRIPTION OF THE DRAWINGS

Example embodiments will be more clearly understood from the followingbrief description taken in conjunction with the accompanying drawings.The accompanying drawings represent non-limiting, example embodiments asdescribed herein.

FIG. 1 is a sectional view illustrating a semiconductor device accordingto example embodiments of present inventive concepts.

FIGS. 2 through 8 are sectional views illustrating a process offabricating a semiconductor device, whose section is shaped like that ofFIG. 1.

FIG. 9 is a sectional view illustrating a semiconductor device accordingto example embodiments of present inventive concepts.

FIGS. 10 and 11 are sectional views illustrating a process offabricating a semiconductor device, whose section is shaped like that ofFIG. 9.

FIG. 12 is a schematic block diagram illustrating an example of memorysystems including a semiconductor device according to exampleembodiments of present inventive concepts.

It should be noted that these figures are intended to illustrate thegeneral characteristics of methods, structure and/or materials utilizedin certain example embodiments and to supplement the written descriptionprovided below. These drawings are not, however, to scale and may notprecisely reflect the precise structural or performance characteristicsof any given embodiment, and should not be interpreted as defining orlimiting the range of values or properties encompassed by exampleembodiments. For example, the relative thicknesses and positioning ofmolecules, layers, regions and/or structural elements may be reduced orexaggerated for clarity. The use of similar or identical referencenumbers in the various drawings is intended to indicate the presence ofa similar or identical element or feature.

DETAILED DESCRIPTION

Example embodiments of present inventive concepts will now be describedmore fully with reference to the accompanying drawings, in which exampleembodiments are shown. Example embodiments of present inventive conceptsmay, however, be embodied in many different forms and should not beconstrued as being limited to the embodiments set forth herein; rather,these embodiments are provided so that this disclosure will be thoroughand complete, and will fully convey the concept of example embodimentsto those of ordinary skill in the art. In the drawings, the thicknessesof layers and regions are exaggerated for clarity. Like referencenumerals in the drawings denote like elements, and thus theirdescription will be omitted.

It will be understood that when an element is referred to as being“connected” or “coupled” to another element, it can be directlyconnected or coupled to the other element or intervening elements may bepresent. In contrast, when an element is referred to as being “directlyconnected” or “directly coupled” to another element, there are nointervening elements present. Like numbers indicate like elementsthroughout. As used herein the term “and/or” includes any and allcombinations of one or more of the associated listed items. Other wordsused to describe the relationship between elements or layers should beinterpreted in a like fashion (e.g., “between” versus “directlybetween,” “adjacent” versus “directly adjacent,” “on” versus “directlyon”).

It will be understood that, although the terms “first”, “second”, etc.may be used herein to describe various elements, components, regions,layers and/or sections, these elements, components, regions, layersand/or sections should not be limited by these terms. These terms areonly used to distinguish one element, component, region, layer orsection from another element, component, region, layer or section. Thus,a first element, component, region, layer or section discussed belowcould be termed a second element, component, region, layer or sectionwithout departing from the teachings of example embodiments.

Spatially relative terms, such as “beneath,” “below,” “lower,” “above,”“upper” and the like, may be used herein for ease of description todescribe one element or feature's relationship to another element(s) orfeature(s) as illustrated in the figures. It will be understood that thespatially relative terms are intended to encompass differentorientations of the device in use or operation in addition to theorientation depicted in the figures. For example, if the device in thefigures is turned over, elements described as “below” or “beneath” otherelements or features would then be oriented “above” the other elementsor features. Thus, the example term “below” can encompass both anorientation of above and below. The device may be otherwise oriented(rotated 90 degrees or at other orientations) and the spatially relativedescriptors used herein interpreted accordingly.

The terminology used herein is for the purpose of describing particularembodiments only and is not intended to be limiting of exampleembodiments. As used herein, the singular forms “a,” “an” and “the” areintended to include the plural forms as well, unless the context clearlyindicates otherwise. It will be further understood that the terms“comprises”, “comprising”, “includes” and/or “including,” if usedherein, specify the presence of stated features, steps, operations,elements and/or components, but do not preclude the presence or additionof one or more other features, steps, operations, elements, componentsand/or groups thereof.

Unless otherwise defined, all terms (including technical and scientificterms) used herein have the same meaning as commonly understood by oneof ordinary skill in the art to which example embodiments of presentinventive concepts belong. It will be further understood that terms,such as those defined in commonly-used dictionaries, should beinterpreted as having a meaning that is consistent with their meaning inthe context of the relevant art and will not be interpreted in anidealized or overly formal sense unless expressly so defined herein.

FIG. 1 is a sectional view illustrating a semiconductor device accordingto example embodiments of present inventive concepts.

Referring to FIG. 1, an interlayer insulating layer 3 may be provided ona substrate 1 including a first region A and a second region B. In someembodiments, a device isolation layer and transistors may be provided onthe substrate 1. Further, conductive patterns 10 a, 10 b, and 10 c maybe provided on the interlayer insulating layer 3. In some embodiments,the conductive patterns 10 a, 10 b, and 10 c may be provided in the formof a plurality of lines extending along a specific direction, and insome example embodiments, each of them may be provided in the form of acontact plug or of an interconnection structure including a contact plugand a conductive line. In some embodiments, at least one of theconductive patterns 10 a, 10 b, and 10 c may be electrically connectedto contact plugs or interconnection lines, which may be provided in theinterlayer insulating layer 3. The conductive patterns 10 a, 10 b, and10 c may include first conductive patterns 10 a disposed on the firstregion A, second conductive patterns 10 b disposed on the second regionB, and a third conductive pattern 10 c disposed on a boundary betweenthe first and second regions A and B. A first space D1 between the firstconductive patterns 10 a may be smaller than a second space D2 betweenthe second conductive patterns 10 b. In certain embodiments, the thirdconductive pattern 10 c may be one of the first conductive patterns 10 alocated most adjacent (e.g., closest) to the second region B or one ofthe second conductive patterns 10 b located most adjacent (e.g.,closest) to the first region A. A space between the third conductivepattern 10 c and the first conductive pattern 10 a adjacent thereto maybe equal to the space between the first conductive patterns 10 a. Aspace between the third conductive pattern 10 c and the secondconductive pattern 10 b adjacent thereto may be equal to the spacebetween the second conductive patterns 10 b.

Each of the conductive patterns 10 a, 10 b, and 10 c may include aninterconnection line portion 7 and a metal diffusion barrier layer 5covering side and bottom surfaces thereof. Top surfaces of theconductive patterns 10 a, 10 b, and 10 c may be covered with aprotection layer 9. The interconnection line portion 7 may be formed ofa low-resistance conductive material (e.g., copper, tungsten, oraluminum). The diffusion barrier layer 5 may be formed of at least oneselected from the group consisting of titanium (Ti), titanium nitride(TiN), tantalum (Ta), tantalum nitride (TaN), ruthenium (Ru), cobalt(Co), manganese (Mn), tungsten nitride (WN), nickel (Ni), and nickelboron (NiB). The protection layer 9 may be formed of at least one ofmetals (for example, including tantalum, ruthenium, cobalt, manganese,titanium, tungsten, nickel, and/or aluminum), oxides of the metals,nitrides of the metals, or oxynitrides of the metals.

An insulating diffusion barrier layer 11 may be provided to cover notonly top and side surfaces of the conductive patterns 10 a, 10 b, and 10c but also a top surface of the interlayer insulating layer 3. Theinsulating diffusion barrier layer 11 may be provided to have first andsecond thicknesses T1 and T2 on the first and second regions A and B,respectively, when measured on the interlayer insulating layer 3, and insome embodiments, the first thickness T1 may be smaller than the secondthickness T2. Further, the insulating diffusion barrier layer 11 may beprovided to have third and fourth thicknesses T3 and T4 on sidewalls ofthe first and second conductive patterns 10 a and 10 b, respectively,when measured at the same level, and, in some embodiments, the thirdthickness T3 may be smaller than the fourth thickness T4. The insulatingdiffusion barrier layer 11 may have the third thickness T3 on a sidewallof the third conductive pattern 10 c adjacent to the first region A andthe fourth thickness T4, which is thicker than the third thickness T3,on an opposite sidewall of the third conductive pattern 10 c adjacent tothe second region B. In some embodiments, the fourth thickness T4 of theinsulating diffusion barrier layer 11 may be equal to or greater than 70Å.

The insulating diffusion barrier layer 11 may be formed to define firstair gaps AG1 between the first conductive patterns 10 a and between thethird conductive pattern 10 c and the first conductive pattern 10 aadjacent thereto. The insulating diffusion barrier layer 11 may beformed of at least one of silicon carbon nitride (SiCN), silicon nitride(SiN), or silicon oxycarbide (SiOC).

A permeable layer 13 may be provided on the insulating diffusion barrierlayer 11 to span the first region A and the second region B. In certainembodiments, the permeable layer 13 may be formed of at least one ofcarbon-doped hydrogenated silicon oxide (SiOCH), low-temperaturetetraethoxysilane (TEOS), or the mixture therof. The permeable layer 13,in conjunction with the insulating diffusion barrier layer 11 on thesecond region B, may define second air gaps AG2 between the secondconductive patterns 10 b and between the third conductive pattern 10 cand the second conductive pattern 10 b adjacent thereto.

For the semiconductor device of FIG. 1, the air gap AG2 may be providedon the second region B, in which the second conductive patterns 10 b arespaced apart from each other with a large space, and this may make itpossible to reduce Resistor-Capacitor (RC) delay between conductivepatterns and thereby increase a signal transfer speed of the device.

A process of fabricating the semiconductor device of FIG. 1 will bedescribed with reference to FIGS. 2 through 8.

FIGS. 2 through 8 are sectional views illustrating the process offabricating a semiconductor device, whose section is shaped like that ofFIG. 1.

Referring to FIG. 2, an interlayer insulating layer 3 may be formed on asubstrate including a first region A and a second region B. Theinterlayer insulating layer 3 may be patterned to form recess regions 4a, 4 b, and 4 c. The recess regions 4 a, 4 b, and 4 c may include firstrecess regions 4 a formed on the first region A, second recess regions 4b formed on the second region B, and a third recess region 4 c formed ona boundary between the first and second regions A and B. Spaces betweenthe first recess regions 4 a and between the third recess region 4 c andthe first recess region 4 a adjacent thereto may be a first space D1.Spaces between the second recess regions 4 b and between the thirdrecess region 4 c and the second recess region 4 b adjacent thereto maybe a second space D2. The first space D1 may be smaller than the secondspace D2.

Referring to FIG. 3, a metal diffusion barrier layer 5 may beconformally formed on the interlayer insulating layer 3, and then, aconductive layer may be formed to fill the recess regions 4 a, 4 b, and4 c having the metal diffusion barrier layer 5. A planarizing orpolishing process may be performed to the conductive layer and the metaldiffusion barrier layer 5 to expose a top surface of the interlayerinsulating layer 3 without removing the metal diffusion barrier layer 5and an interconnection line portion 7 from each of the recess regions 4a, 4 b, and 4 c. Accordingly, conductive patterns 10 a, 10 b, and 10 cmay be formed in the recess regions 4 a, 4 b, and 4 c, respectively. Insome embodiments, spaces between the conductive patterns 10 a, 10 b, and10 c may be given/defined by spaces between the recess regions 4 a, 4 b,and 4 c.

Referring to FIG. 4, a protection layer 9 may be formed on theconductive patterns 10 a, 10 b, and 10 c. The protection layer 9 may beformed using, for example, a deposition process.

Referring to FIG. 5, the interlayer insulating layer 3 may be etched inan etch-back manner to expose side surfaces of the conductive patterns10 a, 10 b, and 10 c. Here, owing to the presence of the protectionlayer 9, it may be possible to protect the interconnection line portion7 from being damaged in the etch-back process.

As described with reference to FIGS. 2 through 5, a damascene processmay be used to form the conductive patterns 10 a, 10 b, and 10 c. Byusing the damascene process, the interconnection line portion 7 can beformed of copper that is hardly etched (e.g., etching of the copper maybe reduced).

In some embodiments, the process of forming the conductive patterns 10a, 10 b, and 10 c is not limited to the damascene process. For example,the conductive patterns 10 a, 10 b, and 10 c may be formed by depositinga conductive layer on an interlayer insulating layer 3 and thenpatterning the conductive layer.

Referring to FIG. 6, an insulating diffusion barrier layer 11 may beprovided on a front side of the substrate 1. In certain embodiments, theinsulating diffusion barrier layer 11 may be formed using a depositionprocess exhibiting a poor step coverage property (e.g., a sputteringprocess or a physical vapor deposition process). For example, theinsulating diffusion barrier layer 11 may be thicker on top surfaces ofthe conductive patterns 10 a, 10 b, and 10 c than on side surfaces ofthe conductive patterns 10 a, 10 b, and 10 c and a top surface of theinterlayer insulating layer 3. Accordingly, the insulating diffusionbarrier layer 11 may have overhang portions closing top entrances ofnarrow regions (e.g., of the first space D1) between the firstconductive patterns 10 a and between the third conductive pattern 10 cand the first conductive pattern 10 a adjacent thereto and therebydefining first air gaps AG1. By contrast, wide regions between thesecond conductive patterns 10 b and between the third conductive pattern10 c and the second conductive pattern 10 b adjacent thereto may not beclosed by the insulating diffusion barrier layer 11. As described withreference to FIG. 1, the insulating diffusion barrier layer 11 may havea position-dependent thickness (e.g., the thicknesses T1, T2, T3, andT4).

Referring to FIG. 7, a sacrificial layer may be formed and be etched toform sacrificial layer patterns 15 on the second region B. For example,the sacrificial layer patterns 15 may be formed to fill spaces betweenthe second conductive patterns 10 b and between the third conductivepattern 10 c and the second conductive pattern 10 b adjacent thereto. Insome embodiments, due to the presence of the insulating diffusionbarrier layer 11, the sacrificial layer pattern 15 may not be formed onthe first region A. The sacrificial layer pattern 15 may be formed of alayer of hydrocarbon (C_(x)H_(y)), which may be formed by aspin-on-dielectrics (SOD) process or a Plasma-Enhanced Chemical VaporDeposition (PE-CVD) process.

Referring to FIGS. 8 and 1, a permeable layer 13 may be formed on theinsulating diffusion barrier layer 11 and the sacrificial layer pattern15. An ashing process may be performed to selectively remove thesacrificial layer pattern 15. The ashing process may be performed bysupplying gas (e.g., at least one of Ammonia (NH₃), Hydrogen (H₂),Nitrous Oxide (N₂O), Oxygen (O₂), Carbon Dioxide (CO₂), or CarbonMonoxide (CO)) capable of producing a hydrogen radical or oxygen radicalat a temperature of 20-400° C. The hydrogen or oxygen radical producedin the ashing process may pass through the permeable layer 13 and reactwith hydrocarbon of the sacrificial layer pattern 15. As the result ofthe reaction, the sacrificial layer pattern 15 may be transformed from asolid phase to a gas phase (e.g., methane (CH₃), carbon dioxide (CO₂),or carbon monoxide (CO)), and the gas may be exhausted to the outsidethrough the permeable layer 13. In other words, the sacrificial layerpattern 15 may be removed, and consequently second air gaps AG2 mayreplace the sacrificial layer patterns 15. Since the insulatingdiffusion barrier layer 11 with a thickness of 70 Å or thicker coversthe sidewalls of the second and third conductive patterns 10 b and 10 con the second region B, oxygen may not infiltrate into the second andthird conductive patterns 10 b and 10 c, during the ashing process.Accordingly, it may be possible to protect the conductive patterns 10 a,10 b, and 10 c from being damaged or oxidized.

As a result, it may be possible to form air gaps between interconnectionlines with various intervals or pitches.

FIG. 9 is a sectional view illustrating a semiconductor device accordingto some example embodiments of present inventive concepts.

Referring to FIG. 9, a first interconnection structure L1 and a secondinterconnection structure L2 may be sequentially stacked on a substrate1 with a first region A and a second region B. Except for a differenceassociated with the permeable layer, the first interconnection structureL1 may be configured to have substantially the same or similar structureas the interconnection line of FIG. 1. For example, the firstinterconnection structure L1 may include an interlayer insulating layer3, conductive patterns 10 a, 10 b, and 10 c on the interlayer insulatinglayer 3, a first protection layer 9 a on the conductive patterns 10 a,10 b, and 10 c, a first insulating diffusion barrier layer 11 a coveringthe conductive patterns 10 a, 10 b, and 10 c with the first protectionlayer 9 a, and air gaps AG1 and AG2 between the conductive patterns 10a, 10 b, and 10 c. The second interconnection structure L2 may have astructure similar to the first interconnection structure L1, but theconductive patterns 10 a, 10 b, and 10 c thereof may be provided on afirst permeable layer 13 a, in place of the interlayer insulating layer3. In other words, the second interconnection structure L2 may includethe first permeable layer 13 a, the conductive patterns 10 a, 10 b, and10 c on the first permeable layer 13 a, a second protection layer 9 b onthe conductive patterns 10 a, 10 b, and 10 c, and a second insulatingdiffusion barrier layer 11 b covering the conductive patterns 10 a, 10b, and 10 c with the second protection layer 9 b, and air gaps AG1 andAG2 between the conductive patterns 10 a, 10 b, and 10 c. The secondinterconnection structure L2 may be covered with a second permeablelayer 13 b. In certain embodiments, the protection layers 9 a and 9 bmay be provided to have substantially the same features as theprotection layer 9 of FIG. 1. The insulating diffusion barrier layers 11a and 11 b may be provided to have substantially the same features asthe insulating diffusion barrier layer 11 described with reference toFIG. 1. The permeable layers 13 a and 13 b may be provided to havesubstantially the same features as the permeable layer 13 described withreference to FIG. 1. Other elements may also be configured to havesubstantially the same features as corresponding ones of FIG. 1.

FIGS. 10 and 11 are sectional views illustrating a process offabricating a semiconductor device, whose section is shaped like that ofFIG. 9.

Referring to FIG. 10, a first permeable layer 13 a may be formed on thestructure of FIG. 7. Here, the first permeable layer 13 a may be formedto have a thickness larger than that of FIG. 8. Thereafter, recessregions 4 a, 4 b, and 4 c may be formed in the first permeable layer 13a, in a similar manner to the method described with reference to FIG. 2.

Referring to FIG. 11, conductive patterns 10 a, 10 b, and 10 cconstituting a second interconnection structure L2 may be formed in therecess regions 4 a, 4 b, and 4 c, respectively, in a similar manner tothe method described with reference to FIG. 3. A second protection layer9 b may be formed on top surfaces of the conductive patterns 10 a, 10 b,and 10 c, in a similar manner to the method described with reference toFIG. 4. Thereafter, the first permeable layer 13 a may be etched to thinthe first permeable layer 13 a and expose sidewalls of the conductivepatterns 10 a, 10 b, and 10 c constituting the second interconnectionstructure L2, in a similar manner to the method described with referenceto FIG. 5.

Referring to FIG. 9, an ashing process may be performed to selectivelyremove the sacrificial layer pattern 15, which is positioned in thefirst interconnection structure L1. As a result of the ashing process,the second air gap AG2 may be formed in the first interconnectionstructure L1. Thereafter, a second insulating diffusion barrier layer 11b, air gaps AG1 and AG2, and a second permeable layer 13 b may be formedin a similar manner to the method described with reference to FIGS. 6through 8, thereby forming the second interconnection structure L2.

FIG. 12 is a schematic block diagram illustrating an example of memorysystems including a semiconductor device according to exampleembodiments of present inventive concepts.

Referring to FIG. 12, a memory system 1100 can be applied to a personaldigital assistant (PDA), a portable computer, a web tablet, a wirelessphone, a mobile phone, a digital music player, a memory card and/or allthe devices that can transmit and/or receive data in a wirelesscommunication environment.

The memory system 1100 includes a controller 1110, an input/outputdevice 1120 such as a keypad and a display device, a memory 1130, aninterface 1140 and a bus 1150. The memory 1130 and the interface 1140communicate with each other through the bus 1150.

The controller 1110 includes at least one microprocessor, at least onedigital signal processor, at least one micro controller or other processdevices similar to the microprocessor, the digital signal processor andthe micro controller. The memory 1130 may be used to store aninstruction executed by the controller 1110. The input/output device1120 can receive data or a signal from the outside of the system 1100 ortransmit data or a signal to the outside of the system 1100. Forexample, the input/output device 1120 may include a keyboard, a keypadand/or a display.

The memory 1130 includes at least one of the nonvolatile memory devicesaccording to example embodiments of present inventive concepts. Thememory 1130 may further include a different kind of memory, a volatilememory device capable of random access and various kinds of memories.

The interface 1140 transmits data to a communication network or receivesdata from a communication network.

According to example embodiments of present inventive concepts, asemiconductor device may include an air gap provided on a region, inwhich conductive patterns are spaced apart from each other with a largespace. This makes it possible to reduce RC delay between the conductivepatterns and thereby to increase a signal transfer speed of the device.

According to example embodiments of present inventive concepts, a methodof fabricating a semiconductor device may include selectively forming asacrificial pattern between largely-separated second conductivepatterns, but not between closely-separated first conductive patterns.Sidewalls of the second conductive patterns may be covered with aninsulating diffusion barrier layer having a thickness of 70 Å orthicker, and thus, it may be possible to impede oxygen from infiltratinginto the second conductive pattern during an ashing process for removingthe sacrificial layer pattern and thereby to protect the secondconductive pattern from being damaged.

According to example embodiments of present inventive concepts, by usingthe fabrication method, it may be possible to form air gaps betweeninterconnection lines with various intervals or pitches. Moreover,although air gaps have been discussed herein by way of example, any gapmay be used according to various embodiments of the present disclosure.A gap may be defined, for example, as any void, cavity, or unobstructedspace, and may be a gap filled with air (e.g., an air gap), a gap filledwith an inert gas or gases (e.g., an inert gas gap), a gap defining avacuum (e.g., a vacuum gap), etc.

While example embodiments of present inventive concepts have beenparticularly shown and described, it will be understood by one ofordinary skill in the art that variations in form and detail may be madetherein without departing from the spirit and scope of the attachedclaims.

What is claimed is:
 1. A semiconductor device, comprising: a substrateincluding first and second regions; a plurality of first conductivepatterns on the first region and a plurality of second conductivepatterns on the second region; an insulating diffusion barrier layer onsidewalls of the first and second conductive patterns; a permeable layeron the insulating diffusion barrier layer; a first gap between adjacentones of the plurality of first conductive patterns; and a second gapbetween adjacent ones of the plurality of second conductive patterns,wherein the first gap is defined by first sidewalls and an upper surfaceof the insulating diffusion barrier layer, and wherein the second gap isdefined by second sidewalls of the insulating diffusion barrier layerand a bottom surface of the permeable layer.
 2. The semiconductor deviceof claim 1, wherein the permeable layer is spaced apart from the firstgap.
 3. The semiconductor device of claim 1, wherein the insulatingdiffusion barrier layer comprises a first thickness defining a bottom ofthe first gap that is thinner than a second thickness of the insulatingdiffusion barrier layer defining a bottom of the second gap.
 4. Thesemiconductor device of claim 1, wherein the insulating diffusionbarrier layer comprises a first thickness on the sidewalls of the firstconductive patterns that is thinner than a second thickness of theinsulating diffusion barrier layer on the sidewalls of the secondconductive patterns.
 5. The semiconductor device of claim 1, wherein thepermeable layer is on both of the first and second regions.
 6. Thesemiconductor device of claim 1, further comprising a third conductivepattern on a boundary between the first and second regions, wherein theinsulating diffusion barrier layer is on opposing third and fourthsidewalls of the third conductive pattern, and wherein the insulatingdiffusion barrier layer comprises a first thickness on the thirdsidewall of the third conductive pattern adjacent the first region thatis thinner than a second thickness of the insulating diffusion barrierlayer on the fourth sidewall of the third conductive pattern that isadjacent the second region.
 7. The semiconductor device of claim 1,further comprising a protection layer between the insulating diffusionbarrier layer and upper surfaces of the first and second conductivepatterns.
 8. The semiconductor device of claim 1, further comprising ametal diffusion barrier layer on sidewalls and bottoms ofinterconnection line portions of the first and second conductivepatterns.
 9. The semiconductor device of claim 1, wherein the permeablelayer comprises at least one of carbon-doped hydrogenated silicon oxide(SiOCH), low-temperature tetraethoxysilane (TEOS), and a mixturethereof.
 10. A semiconductor device, comprising: a plurality of firstconductive patterns on a substrate; a first insulating diffusion barrierlayer on sidewalls of the first conductive patterns; a first permeablelayer on the first insulating diffusion barrier layer; a plurality ofsecond conductive patterns on the first permeable layer; a secondinsulating diffusion barrier layer on sidewalls of the second conductivepatterns; a second permeable layer on the second insulating diffusionbarrier layer; a first gap between adjacent ones of the plurality offirst conductive patterns; and a second gap between adjacent ones of theplurality of second conductive patterns, wherein the first gap isdefined by sidewalls and an upper surface of the first insulatingdiffusion barrier layer, and wherein the second gap is defined bysidewalls of the second insulating diffusion barrier layer and a bottomsurface of the second permeable layer.
 11. The semiconductor device ofclaim 10, wherein the first permeable layer is spaced apart from thefirst gap.
 12. The semiconductor device of claim 10, wherein the firstinsulating diffusion barrier layer comprises a first thickness defininga bottom of the first gap that is thinner than a second thickness of thesecond insulating diffusion barrier layer defining a bottom of thesecond gap.
 13. The semiconductor device of claim 10, further comprisinga protection layer between the first insulating diffusion barrier layerand upper surfaces of the first conductive patterns.
 14. Thesemiconductor device of claim 10, further comprising a protection layerbetween the second insulating diffusion barrier layer and upper surfacesof the second conductive patterns.
 15. The semiconductor device of claim10, further comprising a metal diffusion barrier layer on sidewalls andbottoms of interconnection line portions of the first conductivepatterns.
 16. The semiconductor device of claim 10, further comprising ametal diffusion barrier layer on sidewalls and bottoms ofinterconnection line portions of the second conductive patterns.
 17. Thesemiconductor device of claim 10, wherein the first permeable layercomprises at least one of carbon-doped hydrogenated silicon oxide(SiOCH), low-temperature tetraethoxysilane (TEOS), and a mixturethereof.
 18. The semiconductor device of claim 10, wherein the secondpermeable layer comprises at least one of carbon-doped hydrogenatedsilicon oxide (SiOCH), low-temperature tetraethoxysilane (TEOS), and amixture thereof.
 19. A semiconductor device, comprising: a plurality offirst conductive patterns on a substrate; a first insulating diffusionbarrier layer on sidewalls of the first conductive patterns; a firstpermeable layer on the first insulating diffusion barrier layer; aplurality of second conductive patterns on the first permeable layer; asecond insulating diffusion barrier layer on sidewalls of the secondconductive patterns; a second permeable layer on the second insulatingdiffusion barrier layer; a first gap between adjacent ones of theplurality of first conductive patterns; and a second gap betweenadjacent ones of the plurality of second conductive patterns, whereinthe first gap is defined by sidewalls of the first insulating diffusionbarrier layer and a bottom surface of the first permeable layer, andwherein the second gap is defined by sidewalls and an upper surface ofthe second insulating diffusion barrier layer.
 20. The semiconductordevice of claim 19, wherein the second permeable layer is spaced apartfrom the second gap.